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Di-μ-thiocyanato-κ4N:N-bis({2-[2-(methylamino)ethyliminomethyl]phenolato}copper(II))

✍ Scribed by Wei, Yi-Jun ;Wang, Feng-Wu ;Zhu, Qi-Yong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
893 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [Cu 2 (NCS) 2 -(C 10 H 13 N 2 O) 2 ], contains one-half of the centrosymmetric dinuclear complex, which exhibits a CuÁ Á ÁCu separation of 3.255 (2) A ˚. In the complex, each Cu II ion is pentacoordinated in a square-pyramidal geometry. The basal plane is formed by one phenol O [Cu-O = 1.910 (4) A ˚], one imine N [Cu-N = 1.922 (5) A ˚] and one amine N [Cu-N = 2.041 (5) A ˚] atoms from the Schiff base ligand, and by the N atom [Cu-N = 1.940 (6) A ˚] from a thiocyanate ligand. The apical position is occupied by the N atom [Cu-N = 2.768 (6) A ˚] of another thiocyanate ligand. There are intramolecular N-HÁ Á ÁO hydrogen bonds linking the two ligands.

📜 SIMILAR VOLUMES

{4-Bromo-2-[2-(ethylamino)ethyliminometh
{4-Bromo-2-[2-(ethylamino)ethyliminomethyl]phenolato-κ3N,N′,O}(thiocyanato-κN)copper(II)
✍ Zhou, Zhi ;Tang, Rui-Ren 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 306 KB

In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.

catena-Poly[[bis(thiocyanato-κN)cobalt(I
catena-Poly[[bis(thiocyanato-κN)cobalt(II)]-μ-di-4-pyridylamine-κ2N:N′]
✍ Springsteen, Caleb H. ;LaDuca, Robert L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 943 KB

In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands

trans-Bis{2-[3-(cyclohexylamino)propylim
trans-Bis{2-[3-(cyclohexylamino)propyliminomethyl]phenolato-κ2N,O}bis(thiocyanato-κN)iron(II)
✍ Chen, Kun ;Zhang, Ying-Lao ;Feng, Ming-Qian ;Liu, Chang-Hong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 705 KB

The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anion