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trans-Bis{2-[3-(cyclohexylamino)propyliminomethyl]phenolato-κ2N,O}bis(thiocyanato-κN)iron(II)

✍ Scribed by Chen, Kun ;Zhang, Ying-Lao ;Feng, Ming-Qian ;Liu, Chang-Hong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
705 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anions. The Schiff base was obtained by condensation of equimolar amounts of salicylaldehyde and N-cyclohexyl-1,3diaminopropane in acetonitrile. The crystal structure involves intermolecular N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds.

📜 SIMILAR VOLUMES

Bis(μ-azido-κ2N,N)bis({2-[3-(dimethylami
Bis(μ-azido-κ2N,N)bis({2-[3-(dimethylamino)propyliminomethyl]-4-nitrophenolato-κ3O,N,N′}copper(II))
✍ Hou, Hai-Yun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 405 KB

The title complex, [Cu 2 (N 3 ) 2 (C 12 H 16 N 3 O 3 ) 2 ], is an azidebridged dinuclear copper(II) complex. There is a crystallographic inversion centre at the mid-point of the CuÁ Á ÁCu vector. Each Cu atom is coordinated by one O and two N atoms of one Schiff base ligand and two bridging N atoms