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trans-Bis{2-[3-(cyclo­hexyl­amino)­propyl­imino­methyl]­phenolato-κ3O,N,N′}cobalt(III) perchlorate

✍ Scribed by You, Zhong-Lu ;Qu, Yang ;Liu, Wei-Sheng ;Tan, Min-Yu ;Zhu, Hai-Liang

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
418 KB
Volume
59
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê Disorder in solvent or counterion R factor = 0.075 wR factor = 0.213 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, [Co(C 16 H 21 Cl 2 N 2 O) 2 ]ClO 4 , possesses two independent half-molecules of the cation in the asymmetric unit. The symmetry of both cations is C i . The Co III atoms are six-coordinated by four N and two O atoms from two Schiff bases, forming slightly distorted octahedral co