(3,3′-Diamino-2,2′-bipyridine-κ2N,N′)bis(thiocyanato-κN)copper(II)
✍ Scribed by Zhang, Shi-Guo ;Chen, Ju-Na ;Shi, Jing-Min
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 799 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )(hippurato-jO)copper(II) perchlorate dihydrate
In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.
In the title compound, [Cu(C 10 H 8 N 2 ) 2 (H 2 O)](BF 4 ) 2 , the Cu II atom is coordinated by four N atoms and one O atom in a distorted trigonal-bipyramidal geometry. The Cu-N bond lengths are in the range 1.982 (3)-2.124 (3) A ˚, while the Cu-O distance is 2.035 (4) A ˚. The structure is stabil