Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc(II)]
✍ Scribed by Sun, Jin-Yu ;Wang, Xi-Xi
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 143 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Di-l 1,1 -azido-bis[azido(5,5 0 0 0 -dimethyl-2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )zinc(II)]
📜 SIMILAR VOLUMES
The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.
The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II
The title compound, [Zn(C 15 H 13 ClN 2 O 2 ) 2 (C 5 H 5 N) 2 ], is a centrosymmetric monomer with octahedral geometry about the Zn atom. The molecule is stabilized by intermolecular CÐ HÁ Á ÁO and CÐHÁ Á ÁCl interactions, so forming a threedimensional network.