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Bis{2′-[1-(2-hydroxy-5-chloro­phenyl)­ethyl­idene]­benzohydr­azido-κ2O,N2′}bis­(pyridine-κN)­zinc(II)

✍ Scribed by Ali, Hapipah ;Khamis, Nur Ashikin ;Yamin, Bohari. M.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
429 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Zn(C 15 H 13 ClN 2 O 2 ) 2 (C 5 H 5 N) 2 ], is a centrosymmetric monomer with octahedral geometry about the Zn atom. The molecule is stabilized by intermolecular CÐ HÁ Á ÁO and CÐHÁ Á ÁCl interactions, so forming a threedimensional network.

📜 SIMILAR VOLUMES

Bis{2′-[1-(2-hydroxy­phenyl)­ethyl­idene
Bis{2′-[1-(2-hydroxy­phenyl)­ethyl­idene]­benzohydr­azido}bis­(pyridine-κN)­zinc(II)
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Basirun, W. Jefri ;Yamin, Bohari M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 292 KB

In the centrosymmetric title compound, [Zn(C 15 H 13 N 2 O 2 ) 2 -(C 5 H 5 N) 2 ], the Zn atom is chelated by the O and N atoms of two bidentate ligands. The coordination geometry of the central Zn atom is octahedral. The crystal packing is stabilized by intermolecular CÐHÁ Á ÁO interactions.

{4-Chloro-2′-[1-(5-chloro-2-oxido­phenyl
{4-Chloro-2′-[1-(5-chloro-2-oxido­phenyl)­ethyl­idene-κ3O,N2′,O′]­benzhydr­azido}tris­(pyridine-κN)­nickel(II) pyridine solvate
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Basirun, W. Jefri ;Yamin, Bohari M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 164 KB

The crystal structure of the title compound, [Ni(C 15 H 10 Cl 2- N 2 O 2 )(C 5 H 5 N) 3 ]ÁC 5 H 5 N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The Ni II atom in the complex is coordinated by two O and one N atoms of the meridional tridentate

Bis(μ-5-phenyl­tetrazolate-κ2N2:N3)­bis­
Bis(μ-5-phenyl­tetrazolate-κ2N2:N3)­bis­[(2,2′-bi­pyridine-κ2N,N′)­bis(5-phenyl­tetrazolate-κN2)copper(II)]
✍ Shao, Ze-Huai ;Luo, Jun ;Cai, Rui-Fang ;Zhou, Xi-Geng ;Weng, Lin-Hong ;Chen, Zhe 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.052 wR factor = 0.118 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.