Diaminopropane-j 2 N,N 0 0 0 )[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) bis(perchlorate)
[Tris(2-aminoethyl)amine-κ3N,N′,N′′,N′′′](l-tyrosinato-κ2N,O)nickel(II) iodide dihydrate
✍ Scribed by Pei, Yamei ;Wang, Li
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 356 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ni(C~9~H~10~NO~3~)(C~6~H~18~N~4~)]I·2H~2~O, the Ni^II^ atom is in a slightly distorted octahedral coordination environment. In the crystal structure, extensive hydrogen bonding links molecules into a three-dimensional network.
📜 SIMILAR VOLUMES
2-Methylpropane-1,2-diamine-j 2 N,N 0 0 0 )-[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) diperchlorate
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.030 wR factor = 0.071 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Ni(C 2 H 6 N 5 ) 2 ]Á2H 2 O, the Ni cation (site symmetry 1) is coordinated by four N atoms from two bidenate ligands in a square-planar arrangement. A network of O-HÁ Á ÁN, N-HÁ Á ÁN and N-HÁ Á ÁO hydrogen bonds helps to consolidate the crystal packing.