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(dl-Methio­ninato-κ2N,O)(2,2′,2′′-triamino­triethyl­amine-κ4N,N′,N′′,N′′′)nickel(II) perchlorate dihydrate

✍ Scribed by Yu, Hai-Qiong ;Pei, Ya-Mei ;Wang, Li ;Liu, Zhi-Gang

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
177 KB
Volume
63
Category
Article
ISSN
1600-5368

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In the title compound, [Ni(C 6 H 14 N 2 )(C 6 H 16 N 2 )(H 2 O) 2 ]Cl 2 Á-2H 2 O, the cation lies about a twofold rotation axis. The octahedral complex cation is linked to the Cl À anions by hydrogen bonds to form a layer structure. ## Related literature For other nickel dichloride complexes of s

Bis(biguanido-κ2N,N′)nickel(II) dihydrat
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In the title compound, [Ni(C 2 H 6 N 5 ) 2 ]Á2H 2 O, the Ni cation (site symmetry 1) is coordinated by four N atoms from two bidenate ligands in a square-planar arrangement. A network of O-HÁ Á ÁN, N-HÁ Á ÁN and N-HÁ Á ÁO hydrogen bonds helps to consolidate the crystal packing.