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Diaqua(cyclohexane-1,2-diamine-κ2N,N′)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)nickel(II) dichloride dihydrate

✍ Scribed by Zhang, Yu-Zhen ;Chen, Zi-Lu ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
931 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Ni(C 6 H 14 N 2 )(C 6 H 16 N 2 )(H 2 O) 2 ]Cl 2 Á-2H 2 O, the cation lies about a twofold rotation axis. The octahedral complex cation is linked to the Cl À anions by hydrogen bonds to form a layer structure.

Related literature

For other nickel dichloride complexes of substituted ethylenediamines, see Liang et al. (2007).

📜 SIMILAR VOLUMES

Tris(propane-1,2-diamine-κ2N,N′)zinc(II)
Tris(propane-1,2-diamine-κ2N,N′)zinc(II) dichloride dihydrate
✍ Fowkes, Adrian ;Harrison, William T. A. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 334 KB

In the title compound, [Zn(C 3 H 10 N 2 ) 3 ]Cl 2 Á2H 2 O, a complex three-dimensional network of N-HÁ Á ÁO, N-HÁ Á ÁCl and O-HÁ Á ÁCl hydrogen bonds helps to establish the crystal packing.

Diaquabis(N-ethyl-N′,N′-dimethylethylene
Diaquabis(N-ethyl-N′,N′-dimethylethylenediamine-κ2N,N′)nickel(II) dichloride
✍ Liang, Yu-Ning ;Chen, Zi-Lu ;Zhang, Yu-Zhen ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 924 KB

In the title compound, [Ni(C 6 H 16 N 2 ) 2 (H 2 O) 2 ]Cl 2 , the Ni II cation (site symmetry 1) is coordinated by two N,N-bidentate ligands and two water molecules, resulting in a slightly distorted trans-NiO 2 N 4 octahedron. The complex cations and chloride anions are linked by N-HÁ Á ÁCl and O-H

Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-di
Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-dimethyl-N′-(2-pyridylmethylene-κN)ethane-1,2-diamine-κ2N,N′]nickel(II)} bis(perchlorate)
✍ Diao, Yun-Peng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly dist