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Diaquabis(N-ethyl-N′,N′-dimethylethylenediamine-κ2N,N′)nickel(II) dichloride

✍ Scribed by Liang, Yu-Ning ;Chen, Zi-Lu ;Zhang, Yu-Zhen ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
924 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Ni(C 6 H 16 N 2 ) 2 (H 2 O) 2 ]Cl 2 , the Ni II cation (site symmetry 1) is coordinated by two N,N-bidentate ligands and two water molecules, resulting in a slightly distorted trans-NiO 2 N 4 octahedron. The complex cations and chloride anions are linked by N-HÁ Á ÁCl and O-HÁ Á ÁCl hydrogen bonds into a chain. Related literature For other nickel dichloride complexes of substituted ethylenediamines, see Ide & Norman (2007) and Ihara et al. (1991).


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