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trans-Diaqua­bis(N,N′-dimethyl­ethane-1,2-diamine-κ2N,N′)nickel(II) dichloride dihydrate

✍ Scribed by Moore, Lawrence E. ;Norman, Richard E.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
230 KB
Volume
62
Category
Article
ISSN
1600-5368

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✍ Zhang, Yu-Zhen ;Chen, Zi-Lu ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 931 KB

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Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-di
Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-dimethyl-N′-(2-pyridylmethylene-κN)ethane-1,2-diamine-κ2N,N′]nickel(II)} bis(perchlorate)
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In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly dist