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Diaqua­(ethyl­enediamine)(N,N,N′,N′-tetra­methyl­ethylenediamine)nickel(II) dichloride dihydrate

✍ Scribed by Chen, Zi-Lu ;Zhang, Yu-Zhen ;Liang, Fu-Pei

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
392 KB
Volume
62
Category
Article
ISSN
1600-5368

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Diaqua(cyclohexane-1,2-diamine-κ2N,N′)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)nickel(II) dichloride dihydrate
✍ Zhang, Yu-Zhen ;Chen, Zi-Lu ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 931 KB

In the title compound, [Ni(C 6 H 14 N 2 )(C 6 H 16 N 2 )(H 2 O) 2 ]Cl 2 Á-2H 2 O, the cation lies about a twofold rotation axis. The octahedral complex cation is linked to the Cl À anions by hydrogen bonds to form a layer structure. ## Related literature For other nickel dichloride complexes of s

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Diaquabis(N-ethyl-N′,N′-dimethylethylenediamine-κ2N,N′)nickel(II) dichloride
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In the title compound, [Ni(C 6 H 16 N 2 ) 2 (H 2 O) 2 ]Cl 2 , the Ni II cation (site symmetry 1) is coordinated by two N,N-bidentate ligands and two water molecules, resulting in a slightly distorted trans-NiO 2 N 4 octahedron. The complex cations and chloride anions are linked by N-HÁ Á ÁCl and O-H

Further refinement of di­aqua(1,7,11,17-
Further refinement of di­aqua(1,7,11,17-tetraoxa-2,6,12,16-tetra­aza­cyclo­ei­cosane-N,N′,N′′,N′′′)­nickel(II) dichloride
✍ Kuksa, Vladimir A. ;Wardell, Solange M. S. V. ;Lin, Paul Kong Thoo ;Howie, R. Al 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 229 KB

Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.002 A Ê Disorder in main residue R factor = 0.025 wR factor = 0.063 Data-to-parameter ratio = 13.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.