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(N,N,N′,N′′,N′′-Penta­methyl­diethylenetriamine-κ3N,N′,N′′)(trithio­cyanurato-κ2N,S)zinc(II)

✍ Scribed by Marek, Jaromír ;Trávníček, Zdeněk ;Čermáková, Šárka

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
259 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The structure of the title compound, [Zn(C~9~H~23~N~3~)(C~3~HN~3~S~3~)], consists of discrete molecules connected by N—H...S hydrogen bonds into centrosymmetric dimers. The Zn^II^ atom is pentacoordinated in a deformed trigonal–bipyramidal geometry by three N atoms of a tridentate N,N,N′,N′′,N′′-pentamethyldiethylenetriamine ligand, and one S and one N atoms of a trithiocyanurate dianion bonded as a bidentate ligand. The crystal structure is further stabilized by close contacts of the types C—H...S and C—H...N.

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