Bis(dicyanamido-κN)(di-2-pyridylamine-κ2N,N′)zinc(II)
✍ Scribed by Yu, Xiao-Li ;Fang, Yong ;Huang, Cui-Ying ;Gu, Yuan-Peng ;You, Wan-Sheng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 394 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands
In the title complex, [Ni(C~4~H~5~O~2~)~2~(C~10~H~9~N~3~)(H~2~O)], the Ni atom adopts a square-pyramidal NiO~3~N~2~ geometry, with the water molecule at the apical position and N~2~O~2~ donors in the basal plane. A network of O—H...O and N—H...O hydrogen bonds helps to establish the packing.
In the triclinic form of the title compound, [Cu(C 2 N 3 )(C 10 H 8 N 2 ) 2 ]ClO 4 , the Cu II center is coordinated by five N atoms in a distorted square-pyramidal geometry, which is different from that observed earlier in an orthorhombic polymorph of the same compound.