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Aquabis(but-2-enoato-κO)(di-2-pyridylamine-κ2N,N′)nickel(II)

✍ Scribed by Yu, Jian ;Zhang, Ling

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
470 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Ni(C~4~H~5~O~2~)~2~(C~10~H~9~N~3~)(H~2~O)], the Ni atom adopts a square-pyramidal NiO~3~N~2~ geometry, with the water molecule at the apical position and N~2~O~2~ donors in the basal plane. A network of O—H...O and N—H...O hydrogen bonds helps to establish the packing.

📜 SIMILAR VOLUMES

Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,1
Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,10-phenanthroline-κ2N,N′)cadmium(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 683 KB

The Cd^II^ atom in the title complex, [Cd(C~8~H~5~O~3~)~2~(C~12~H~8~N~2~)(H~2~O)], is coordinated by three O atoms of two formylbenzoate ligands, two N atoms of a 1,10-phenanthroline ligand and one water molecule, giving rise to a trigonal–prismatic coordination geometry. Adjacent complex molecules