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Aqua­(di-2-pyridylamine-κ2N2,N2′)(d-gluconato-κ2O,O′)copper(II) trihydrate

✍ Scribed by Yodoshi, Masahiro ;Odoko, Mamiko ;Okabe, Nobuo

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
382 KB
Volume
62
Category
Article
ISSN
1600-5368

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✍ Zhang, Xin-Yan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 273 KB

In the title complex, [Cu(C 7 H 3 NO 5 )(C 10 H 8 N 2 )(H 2 O)]Á3H 2 O, the Cu II atom has a slightly distorted square-pyramidal coordination geometry, with a basal plane formed by two N atoms of the 2,2 0 -bipyridine ligand and two O atoms of the pyridine-2,6-dicarboxylate N-oxide. The apical posit

Aquabis(but-2-enoato-κO)(di-2-pyridylami
Aquabis(but-2-enoato-κO)(di-2-pyridylamine-κ2N,N′)nickel(II)
✍ Yu, Jian ;Zhang, Ling 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 470 KB

In the title complex, [Ni(C~4~H~5~O~2~)~2~(C~10~H~9~N~3~)(H~2~O)], the Ni atom adopts a square-pyramidal NiO~3~N~2~ geometry, with the water molecule at the apical position and N~2~O~2~ donors in the basal plane. A network of O—H...O and N—H...O hydrogen bonds helps to establish the packing.