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Aqua(2,2′-bipyridine-κ2N,N′)(pyridine-2,6-dicarboxylate N-oxide-κ2O1,O2)copper(II) trihydrate

✍ Scribed by Zhang, Xin-Yan


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
273 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title complex, [Cu(C 7 H 3 NO 5 )(C 10 H 8 N 2 )(H 2 O)]Á3H 2 O, the Cu II atom has a slightly distorted square-pyramidal coordination geometry, with a basal plane formed by two N atoms of the 2,2 0 -bipyridine ligand and two O atoms of the pyridine-2,6-dicarboxylate N-oxide. The apical position is occupied by a water molecule. The crystal structure contains O-HÁ Á ÁO intermolecular hydrogen bonds.


📜 SIMILAR VOLUMES


Penta­aqua-1κ5O-(μ-pyridine-2,6-dicarbox
✍ Liu, Ying ;Dou, Jian-Min ;Wang, Da-Qi ;Zhang, Xian-Xi ;Zhou, Lei 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 302 KB

The title compound, [Mn 2 (C 7 H 3 NO 4 ) 2 (H 2 O) 5 ]Á2H 2 O, has been prepared from the hydrothermal reaction of manganese(II) chloride tetrahydrate and pyridine-2,6-dicarboxylic acid. It is isostructural with the analogous Co II , Ni II , Cu II and Zn II compounds.