Aqua(2,2′-bipyridine-κ2N,N′)(pyridine-2,6-dicarboxylate N-oxide-κ2O1,O2)copper(II) trihydrate
✍ Scribed by Zhang, Xin-Yan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 273 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Cu(C 7 H 3 NO 5 )(C 10 H 8 N 2 )(H 2 O)]Á3H 2 O, the Cu II atom has a slightly distorted square-pyramidal coordination geometry, with a basal plane formed by two N atoms of the 2,2 0 -bipyridine ligand and two O atoms of the pyridine-2,6-dicarboxylate N-oxide. The apical position is occupied by a water molecule. The crystal structure contains O-HÁ Á ÁO intermolecular hydrogen bonds.
📜 SIMILAR VOLUMES
Di-l-pyridine-2,5-dicarboxylato-1j 2 N,O 2 :2jO 5 ;-1jO 5 :2j 2 N,O 2 -bis[aqua(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )cadmium(II)] dihydrate
Aqua(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )(L-malato-j 3 O,O 0 0 0 ,O 0 0 00 0 0 )copper(II)
The title compound, [Mn 2 (C 7 H 3 NO 4 ) 2 (H 2 O) 5 ]Á2H 2 O, has been prepared from the hydrothermal reaction of manganese(II) chloride tetrahydrate and pyridine-2,6-dicarboxylic acid. It is isostructural with the analogous Co II , Ni II , Cu II and Zn II compounds.