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Aqua­(2,2′-bipyridine-κ2N,N′)(l-malato-κ3O,O′,O′′)copper(II)

✍ Scribed by He, Long


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
226 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


Aqua(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )(L-malato-j 3 O,O 0 0 0 ,O 0 0 00 0 0 )copper(II)


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catena-Poly[[aqua(4,4 0 0 0 -dimethyl-2,2 0 0 0 -bipyridine)copper(II)]-l-fumarato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -[aqua-(4,4 0 0 0 -dimethyl-2,2 0 0 0 -bipyridine)copper(II)]l-fumarato-jO:jO 0 0 0 ]

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In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of

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In the title complex, [Cu(C 7 H 3 NO 5 )(C 10 H 8 N 2 )(H 2 O)]Á3H 2 O, the Cu II atom has a slightly distorted square-pyramidal coordination geometry, with a basal plane formed by two N atoms of the 2,2 0 -bipyridine ligand and two O atoms of the pyridine-2,6-dicarboxylate N-oxide. The apical posit

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In the mononuclear title compound, [Cd(C~8~H~5~O~3~)~2~(C~10~H~8~N~2~)(H~2~O)]·H~2~O, the Cd atom is __O__,__O__′-chelated by two 4-formylbenzoate monoanions and __N__,__N__′-chelated by 2,2′-bipyridine. It is also coordinated by a water molecule in a monocapped trigonal-prismatic geometry. The coor