In the title compound, [Zn~2~(C~3~N~3~S~3~)(C~9~H~23~N~3~)~2~]ClO~4~·H~2~O, the dinuclear Zn^II^ metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and an S and an N atom o
(μ3-Trithiocyanurato-κ6N1,S2:N3,S4:N5,S6)tris[(N,N,N′,N′′,N′′-pentamethyldiethylenetriamine-κ3N,N′,N′′)zinc(II)] tris(perchlorate)
✍ Scribed by Marek, Jaromír ;Trávníček, Zdeněk ;Čermáková, Šárka
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 387 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
tris-[(N,N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 0 -pentamethyldiethylenetriaminej 3 N,N 0 0 0 ,N 0 0 00 0 0 )zinc(II)] tris(perchlorate)
Jaromı ´r Marek, a,b * Zdene ˇk Tra ´vnı ´c ˇek b and S ˘a ´rka C ˇerma ´kova ´b
📜 SIMILAR VOLUMES
In the title complex, [Ni~3~(C~9~H~3~O~6~)(C~9~H~23~N~3~)~3~(H~2~O)~3~](ClO~4~)~3~·4.25H~2~O, the three Ni^II^ centres are bridged by a benzene-1,3,5-tricarboxylate(3−) anion (btc). Each of the metal centres is coordinated by three N atoms of a tridentate __N__,__N__,__N__′,__N__′′,__N__′′-pentameth
Diaminopropane-j 2 N,N 0 0 0 )[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) bis(perchlorate)
The structure of the title compound, [Zn(C~9~H~23~N~3~)(C~3~HN~3~S~3~)], consists of discrete molecules connected by N—H...S hydrogen bonds into centrosymmetric dimers. The Zn^II^ atom is pentacoordinated in a deformed trigonal–bipyramidal geometry by three N atoms of a tridentate __N__,__N__,__N__′
Single-crystal X-ray study T = 120 K Mean (C-C) = 0.009 A Some non-H atoms missing R factor = 0.066 wR factor = 0.176 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly dist