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{μ-2-[1-(N,N-Dimethyl­amino)eth­yl]ferrocene-1,1′-diylbis(diphenyl­phosphine)-κ2P:P′}bis­[chloro­gold(I)]

✍ Scribed by Sam, Zolisa A. ;Oskarsson, Åke ;Elmroth, Sofi K. C. ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
144 KB
Volume
61
Category
Article
ISSN
1600-5368

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{μ-2-[1-(N,N-Dimethyl­amino)­eth­yl]ferr
{μ-2-[1-(N,N-Dimethyl­amino)­eth­yl]ferrocene-1,1′-diylbis(diphenyl­phosphine)-κ2P:P′}bis­[thio­cyanato­gold(I)]
✍ Sam, Zolisa A. ;Elmroth, Sofi K. C. ;Roodt, Andreas ;Muller, Alfred J. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

The title compound, [Au~2~Fe(C~38~H~37~NP~2~)(SCN)~2~], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl–phosphine ligand. Selected geometrical parameters for the compound are Au—P = 2.265 (2) and 2.260 (3) Å, Au—S = 2.327 (3) and 2.313 (3) Å, and P—Au—S = 175.61 (9) a

Chloro­(2-{[N-(4-methoxy­benz­yl)methyl­
Chloro­(2-{[N-(4-methoxy­benz­yl)methyl­amino]meth­yl}ferrocene-κ2N,C1)(triphenyl­phosphine-κP)palladium(II)
✍ Wang, Hong-Xing ;Wu, Hong-Fei ;Gao, Ren-Qing ;Geng, Feng-Ying ;Li, Ying-Jie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 154 KB

In the title compound, [PdCl{Fe(C 5 H 5 )(C 15 H 17 NO)}-(C 18 H 15 P)] or [FePd(C 5 H 5 )(C 15 H 17 NO)Cl(C 18 H 15 P)], the Pd II atom is in a slightly distorted square-planar environment. The dihedral angle between the two cyclopentadienyl rings of the ferrocenyl group is 6.4 (1) .