Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.052 wR factor = 0.118 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis[μ2-phenylbis(2-pyridyl)phosphine]-κ3N,N′:P;κ3P:N,N′-bis[chlorocopper(I)]
✍ Scribed by Zhang, Tian-Le ;Wang, Kai-Li ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 156 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 -bis[(2,2 0 0 0 -bipyridinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
The title compound, [Cu 2 (C 15 H 13 ClP) 4 (C 30 H 28 N 2 )](ClO 4 ) 2 , was synthesized by the reaction of 9,10-bis[(n-propylamino)methyl]anthracene and 6-chloro-2-(diphenylphosphino)pyridine with [Cu(CH 3 CN) 4 ]ClO 4 . The Cu atoms adopt a trigonal±planar geometry and the cation is centrosymmetr
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.
Bis[l-bis(diphenylphosphino)aminej 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoridoborate) dichloromethane solvate