Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate
Bis[μ-bis(diphenylphosphino)amine-κ2P:P′]bis[(1,10-phenanthroline-κ2N,N′)copper(I)] bis(tetrafluoridoborate) dichloromethane solvate
✍ Scribed by Mo, Juan ;Qian, Heng-Yu ;Du, Xiang-Dang ;Chen, Wen
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 795 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis[l-bis(diphenylphosphino)aminej 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoridoborate) dichloromethane solvate
📜 SIMILAR VOLUMES
R)-(+)-[l-2,2 0 0 0 -Bis(diphenylphosphino)-1,1 0 0 0 -binaphthalene-j 2 P:P 0 0 0 ]bis[chloridogold(I)] dichloromethane solvate
In the title complex, [Cu 2 I 2 (C 12 H 8 N 2 ) 2 ]ÁC 2 H 3 N, two Cu I atoms are bridged by two I atoms and each Cu I atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org