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Bis(μ-phenyl­phosphido-κ2P:P)­bis{[1,2-(di­cyclo­hexyl­phosphino)­ethane-κ2P,P′]­platinum(I)} dichloride bis­(di­chloro­methane) hexane solvate

✍ Scribed by Jaska, Cory A. ;Lough, Alan J. ;Manners, Ian


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
251 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5

For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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Bis­[bis­(di­cyclo­hexyl­phosphino)­etha
✍ Clegg, William ;Scott, Andrew J. ;Wiesauer, Christian ;Weissensteiner, Walter ;M 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 430 KB

In the title complex, [Au(C 26 H 48 P 2 ) 2 ]ClÁ4CHCl 3 , the cation and anion lie on twofold rotation axes. The Au atom has a distorted tetrahedral coordination geometry, with two chelating diphosphine ligands, and lies far from the anion.