Bis[bis(dicyclohexylphosphino)ethane-κ2P,P′]gold(I) chloride chloroform tetrasolvate
✍ Scribed by Clegg, William ;Scott, Andrew J. ;Wiesauer, Christian ;Weissensteiner, Walter ;Marder, Todd B.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 430 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title complex, [Au(C 26 H 48 P 2 ) 2 ]ClÁ4CHCl 3 , the cation and anion lie on twofold rotation axes. The Au atom has a distorted tetrahedral coordination geometry, with two chelating diphosphine ligands, and lies far from the anion.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.020 A Ê R factor = 0.034 wR factor = 0.096 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.