Bis[l-bis(diphenylphosphino)aminej 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoridoborate) dichloromethane solvate
Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(1,10-phenanthroline-κ2N,N′)copper(I)] bis(tetrafluoroborate) dichloromethane disolvate
✍ Scribed by Liu, Huan-Yu ;Wang, Fen-Ying ;Wang, Guo-Yong ;Huang, Chang-Gan ;Peng, Da-Yong
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 160 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate
📜 SIMILAR VOLUMES
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.