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Bis[μ-bis­(diphenyl­phosphino)methane-κ2P:P′]bis­[(1,10-phenanthroline-κ2N,N′)copper(I)] bis­(tetra­fluoro­borate) dichloro­methane disolvate

✍ Scribed by Liu, Huan-Yu ;Wang, Fen-Ying ;Wang, Guo-Yong ;Huang, Chang-Gan ;Peng, Da-Yong


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
160 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate


📜 SIMILAR VOLUMES


Bis­[μ-bis­(di­phenyl­phosphino)­methane
✍ Wu, Mei-Mei ;Zhang, Li-Yi ;Qin, Yong-Hai ;Chen, Zhong-Ning 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 169 KB

The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.