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Bis­[μ-bis­(di­phenyl­phosphino)­methane-κ2P:P′]­bis­[diaceto­nitrile­copper(I)] bis­(hexa­fluoro­phosphate)

✍ Scribed by Wu, Mei-Mei ;Zhang, Li-Yi ;Qin, Yong-Hai ;Chen, Zhong-Ning

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
169 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.

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