Tris[μ-bis(diphenylphosphino)methane-κ2P:P′]di-μ3-chloro-trisilver(I) hexafluoroantimonate dichloromethane disolvate
✍ Scribed by Wu, Mei-Mei ;Qin, Yong-Hai
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 198 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title " 3 -Cl dicapped trisilver compound, [Ag 3 Cl 2 -(C 25 H 22 P 2 ) 3 ][SbF 6 ]Á2CH 2 Cl 2 , exhibits distorted trigonal bipyramidal coordination with two " 3 -Cl atoms at the apices. The Ag I atoms are four-coordinated and exhibit a tetrahedral geometry.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.026 A Ê R factor = 0.066 wR factor = 0.160 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.056 wR factor = 0.166 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.012 A Ê R factor = 0.082 wR factor = 0.234 Data-to-parameter ratio = 20.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.020 A Ê R factor = 0.034 wR factor = 0.096 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.