Bis[l-bis(diphenylphosphino)aminej 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoridoborate) dichloromethane solvate
(R)-(+)-[μ-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene-κ2P:P′]bis[chloridogold(I)] dichloromethane solvate
✍ Scribed by Bats, Jan W. ;Hamzic, Melissa ;Hashmi, A. Stephen K.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 872 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
R)-(+)-[l-2,2 0 0 0 -Bis(diphenylphosphino)-1,1 0 0 0 -binaphthalene-j 2 P:P 0 0 0 ]bis[chloridogold(I)] dichloromethane solvate
📜 SIMILAR VOLUMES
In the centrosymmetric dicationic cyclic title compound [Au 2 (C 25 H 22 P 2 ) 2 ](NO 3 ) 2 Á2CD 3 OD, an aurophilic interaction with a distance of 3.0245 (3) A ˚is found between the lineardicoordinated Au I centres. The perdeuteromethanol solvent molecules are linked to the nitrate anions via hydro
## Data collection Nonius KappaCCD diffractometer Absorption correction: multi-scan DENZO and SCALEPACK (Otwinowski & Minor, 1997) T min = 0.38, T max = 0.45 23737 measured reflections 12197 independent reflections 8452 reflections with I > 3(I) R int = 0.026 Refinement R[F 2 > 2(F 2 )] = 0.036 wR