μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P-bis[trichloridogallium(III)]
✍ Scribed by Cheng, Fei ;Hector, Andrew L. ;Levason, William ;Reid, Gillian ;Webster, Michael ;Zhang, Wenjian
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 488 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In polymeric [Ag(C 2 F 3 O 2 )(C 26 H 24 P 2 )] n , the carboxylate is monodentate to silver, and the two diphosphine ligands that occupy different positions of 1 site symmetry link the Ag(C 2 O 2 F 3 ) units into a chain. The Ag atom shows trigonalplanar coordination.
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.