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catena-Poly[[(trifluoro­acetato-κO)silver(I)]-μ-1,2-bis­(diphenyl­phosphino)ethane-κ2P:P′]

✍ Scribed by Bao, Feng ;Lü, Xing-Qiang ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
219 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In polymeric [Ag(C 2 F 3 O 2 )(C 26 H 24 P 2 )] n , the carboxylate is monodentate to silver, and the two diphosphine ligands that occupy different positions of 1 site symmetry link the Ag(C 2 O 2 F 3 ) units into a chain. The Ag atom shows trigonalplanar coordination.


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catena-Poly[[trimethyl­tin(IV)]-μ-2-p-to
✍ Hussain, Mukhtiar ;Hanif, Muhammad ;Ali, Saqib ;Butcher, Ray 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 134 KB

The title compound, [Sn(CH~3~)~3~(C~9~H~9~O~2~)], forms polymeric chains involving both O atoms of the carboxylate group. The coordination geometry around the Sn atom is distorted trigonal–bipyramidal.