catena-Poly[[[bis(cyclohexyldiphenylphosphine-κP)silver(I)]-μ-cyano-κ2N:C-silver(I)-μ-cyano-κ2C:N] dichloromethane solvate]
✍ Scribed by Xie, Xiaocong ;Saparov, Bayrammurad ;Yap, Glenn P. A.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 873 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.012 A Ê R factor = 0.058 wR factor = 0.155 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Ag(C~4~H~4~N~2~)]ClO~4~, pyrazine ligands bridge two symmetry-related Ag atoms [Ag—N = 2.222 (3) Å] to form linear polycationic chains which run along the __c__ axis of the orthorhombic unit cell. The Ag^I^ ion has __m__2__m__ site symmetry. The N atoms of the pyrazine ligand
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.133 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.