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Bis[(diphenyl­phosphino)acetato-κ2O,P]palladium(II) dichloro­methane solvate

✍ Scribed by Guo, Meng-Ping ;Jian, Fang-Fang ;He, Ren ;Xiao, Hai-Lian


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
149 KB
Volume
61
Category
Article
ISSN
1600-5368

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✍ Read, Benjamin D. ;Slawin, Alexandra M. Z. ;Woollins, J. Derek 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 171 KB

The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the