cis-Diazido[bis(diphenylphosphino)methane-κ2P,P′]ruthenium(II) dichloromethane 0.42-solvate
✍ Scribed by Russo, Luca ;Nättinen, Kalle ;Vertlib, Viatcheslav ;Rodrigues, João ;Rissanen, Kari
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 164 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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In the title compound, [RuCl(C~26~H~24~P)~2~(H~2~O)]PF~6~·1.5CH~2~Cl~2~·0.5H~2~O, the complex Ru^II^ cation is in a slightly distorted octahedral environment, chelated by two bis(diphenylphosphino)ethane ligands, with a water molecule and a chloride anion in a mutually __cis__ geometry completing th
The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the