Bis(diphenyl­methyl­phosphine-κP)(disulfurdinitrido-κ2N,S)platinum(II) dichloro­methane solvate

✍ Scribed by Read, Benjamin D. ;Slawin, Alexandra M. Z. ;Woollins, J. Derek

• Publisher: International Union of Crystallography
• Year: 2007
• Tongue: English
• Weight: 171 KB
• Volume: 63
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536807006344

✦ Synopsis

The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the published PPh~3~ analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.