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Dichloro­(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N)bis­(triphenyl­phosphine-κP)ruthenium(II) dichloro­methane solvate

✍ Scribed by Song, Yan-Wei ;Yu, Zhan ;Zhang, Qian-Feng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
153 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Dichloro(4,4 0 0 0 -di-tert-butyl-2,2 0 0 0 -bipyridinej 2 N,N)bis(triphenylphosphine-jP)ruthenium(II) dichloromethane solvate

📜 SIMILAR VOLUMES

Bis(diphenyl­methyl­phosphine-κP)(disulf
Bis(diphenyl­methyl­phosphine-κP)(disulfurdinitrido-κ2N,S)platinum(II) dichloro­methane solvate
✍ Read, Benjamin D. ;Slawin, Alexandra M. Z. ;Woollins, J. Derek 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 171 KB

The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the

(SP-4-2)-(4,4′-Di-tert-butyl-2,2′-bipyri
(SP-4-2)-(4,4′-Di-tert-butyl-2,2′-bipyridine-κ2N,N′)diiodidopalladium(II)
✍ Jones, Peter G. ;Fernández-Rodríguez, María J. ;Martínez-Martínez, Antonio J. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 367 KB

In the title compound, [PdI~2~(C~18~H~24~N~2~)], the coordination at the Pd atom is distorted square planar; the ligand bite is 79.19 (17)°. The compound is isotypic with the dichlorido analogue. The Pd—N bond lengths of 2.047 (4) and 2.062 (4)Å are __ca__ 0.03 Å longer than those of the chloride de