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✦   LIBER   ✦

(SP-4-2)-(4,4′-Di-tert-butyl-2,2′-bipyridine-κ2N,N′)diiodidopalladium(II)

✍ Scribed by Jones, Peter G. ;Fernández-Rodríguez, María J. ;Martínez-Martínez, Antonio J.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
367 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [PdI~2~(C~18~H~24~N~2~)], the coordination at the Pd atom is distorted square planar; the ligand bite is 79.19 (17)°. The compound is isotypic with the dichlorido analogue. The Pd—N bond lengths of 2.047 (4) and 2.062 (4)Å are ca 0.03 Å longer than those of the chloride derivative.

📜 SIMILAR VOLUMES

4,4′-Di-tert-butyl-2,2′-bipyridine–hexaf
4,4′-Di-tert-butyl-2,2′-bipyridine–hexafluoro­benzene (1/1)
✍ Batsanov, Andrei S. ;Mkhalid, Ibraheem A. I. ;Marder, Todd B. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 243 KB

The title structure, C~18~H~24~N~2~·C~6~F~6~, comprises mixed stacks of alternating 4,4′-di-__tert__-butyl-2,2′-bipyridine and hexafluorobenzene molecules, both lying on crystallographic mirror planes. There are weak C—H...N (2.46–2.51 Å) and C—H...F (2.52–2.74 Å) hydrogen bonds lying on the mirror

μ-4,4′-Bipyridine-κ2N:N′-bis­[triaqua­(p
μ-4,4′-Bipyridine-κ2N:N′-bis­[triaqua­(pyridine-2,4-dicarboxyl­ato-κ2N,O)cobalt(II)] dihydrate
✍ Zhang, Xian-Ming 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 110 KB

The title centrosymmetric dinuclear complex, [Co 2 -(C 7 H 3 NO 4 ) 2 (C 10 H 8 N 2 )(H 2 O) 6 ]Á2H 2 O, has been synthesized hydrothermally. The cobalt(II) ion is coordinated in a slightly distorted octahedral environment by one N atom and one carboxylate O atom in N,O-chelating mode from one 2,4py