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μ-4,4′-Bipyridine-κ2N:N′-bis[triaqua(pyridine-2,4-dicarboxylato-κ2N,O)cobalt(II)] dihydrate

✍ Scribed by Zhang, Xian-Ming

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 110 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805015473

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✦ Synopsis

The title centrosymmetric dinuclear complex, [Co 2 -(C 7 H 3 NO 4 ) 2 (C 10 H 8 N 2 )(H 2 O) 6 ]Á2H 2 O, has been synthesized hydrothermally. The cobalt(II) ion is coordinated in a slightly distorted octahedral environment by one N atom and one carboxylate O atom in N,O-chelating mode from one 2,4pyridinedicarboxylate ligand, by one N atom from 4,4 0bipyridine, and by three water molecules. O-HÁ Á ÁO hydrogen bonds link molecules into a three-dimensional framework.

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✦ Synopsis

μ-4,4′-Bipyridine-κ2N:N′-bis[triaqua(pyridine-2,4-dicarboxylato-κ2N,O)cobalt(II)] dihydrate