The title centrosymmetric dinuclear complex, [Co 2 -(C 7 H 3 NO 4 ) 2 (C 10 H 8 N 2 )(H 2 O) 6 ]Á2H 2 O, has been synthesized hydrothermally. The cobalt(II) ion is coordinated in a slightly distorted octahedral environment by one N atom and one carboxylate O atom in N,O-chelating mode from one 2,4py
μ-4,4′-Bipyridine-κ2N:N′-bis[triaqua(4,4′-bipyridine-κ2N,N′)[1,3-phenylenedi(oxyacetato)-κO]cobalt(II)] 4,4′-bipyridine heptahydrate
✍ Scribed by Gao, Shan ;Liu, Ji-Wei ;Huo, Li-Hua ;Zhao, Hui ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 263 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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The title complex, [Co(C 10 H 9 O 5 ) 2 (C 10 H 10 O 5 ) 2 (C 5 H 5 N) 2 ], is a neutral mononuclear complex. The Co II atom, which lies on a centre of symmetry, has a distorted octahedral geometry involving two O atoms of the 3-(4-carboxyphenoxy)propionate groups, two O atoms of the 3-(4-carboxyphe
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.089 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.