Bis[(acetato-κO)bis(2,2′-bipyridine-κ2N,N′)copper(II)] 4-carboxyphenoxyacetate hexahydrate
✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Gu, Chang-Sheng ;Zhao, Hui ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 233 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.089 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu(CH~3~CO~2~)~2~(C~9~H~7~N~3~O)~2~(H~2~O)], is a mononuclear complex in which the Cu^II^ atom assumes a square-pyramidal coordination geometry. The Cu atom and the aqua O atom lie on a crystallographic twofold rotation axis. In the crystal structure, there are hydrogen bonds an
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.008 A Ê Disorder in main residue R factor = 0.057 wR factor = 0.134 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 275 K Mean '(C±C) = 0.005 A Ê R factor = 0.037 wR factor = 0.120 Data-to-parameter ratio = 18.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.