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4,4′-Di-tert-butyl-2,2′-bipyridine–hexafluoro­benzene (1/1)

✍ Scribed by Batsanov, Andrei S. ;Mkhalid, Ibraheem A. I. ;Marder, Todd B.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
243 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title structure, C~18~H~24~N~2~·C~6~F~6~, comprises mixed stacks of alternating 4,4′-di-tert-butyl-2,2′-bipyridine and hexafluorobenzene molecules, both lying on crystallographic mirror planes. There are weak C—H...N (2.46–2.51 Å) and C—H...F (2.52–2.74 Å) hydrogen bonds lying on the mirror planes, as well as π–π interactions between stacked aromatic molecules (as indicated by interplanar distances of 3.35 Å).

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