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[Bis(diphenyl­phosphino)methane-κ2P,P′][bis­(diphenyl­thio­phosphin­yl)methane-κ2S,S′]platinum(II) bis­(perchlorate) acetone solvate

✍ Scribed by Alkan, Leman ;İrişli, Sevil


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
155 KB
Volume
61
Category
Article
ISSN
1600-5368

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Bis(diphenyl­methyl­phosphine-κP)(disulf
✍ Read, Benjamin D. ;Slawin, Alexandra M. Z. ;Woollins, J. Derek 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 171 KB

The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the