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cis-Aqua­bis[bis­(diphenyl­phosphino)ethane-κ2P,P′]­chloro­ruthenium(II) hexa­fluoro­phosphate dichloro­methane sesquisolvate hemihydrate

✍ Scribed by Russo, Luca ;Figueira, João ;Rodrigues, João ;Rissanen, Kari

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
163 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [RuCl(C~26~H~24~P)~2~(H~2~O)]PF~6~·1.5CH~2~Cl~2~·0.5H~2~O, the complex Ru^II^ cation is in a slightly distorted octahedral environment, chelated by two bis(diphenylphosphino)ethane ligands, with a water molecule and a chloride anion in a mutually cis geometry completing the coordination.

📜 SIMILAR VOLUMES

[1,1′-Bis(diphenyl­phosphino)cobaltoceni
[1,1′-Bis(diphenyl­phosphino)cobaltocenium-κ2P,P′]chloro­(η5-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) hexa­fluoro­phosphate dichloro­methane hemisolvate
✍ Wu, Xiang-Hua ;Ren, Yong ;Yu, Guang-Ao ;Liu, Sheng-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 281 KB

In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent