[1,1′-Bis(diphenyl­phosphino)cobaltocenium-κ2P,P′]chloro­(η5-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) hexa­fluoro­phosphate dichloro­methane hemisolvate

✍ Scribed by Wu, Xiang-Hua ;Ren, Yong ;Yu, Guang-Ao ;Liu, Sheng-Hua

• Publisher: International Union of Crystallography
• Year: 2006
• Tongue: English
• Weight: 281 KB
• Volume: 62
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536806003011

✦ Synopsis

In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent molecule lies on a twofold rotation axis. In the crystal structure, weak C-HÁ Á ÁF and C-HÁ Á ÁCl hydrogen bonds link molecules into a two-dimensional framework.