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[η5-2-(Diphenyl­phosphino)-1-methyl­cyclo­penta­dien­yl](η5-methyl­cyclo­penta­dien­yl)cobalt(III) hexa­fluoro­phosphate

✍ Scribed by Chen, Yan ;Yu, Guang-Ao ;Meng, Xiang-Gao ;Liu, Sheng-Hua

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
159 KB
Volume
63
Category
Article
ISSN
1600-5368

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Dicarbon­yl(η5-penta­methyl­cyclo­penta­
Dicarbon­yl(η5-penta­methyl­cyclo­penta­dien­yl)(triphenyl­phosphine)iron(II) hexa­fluoro­phosphate
✍ Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 166 KB

In the title compound, [Fe(C 10 H 15 )(C 18 H 15 P)(CO) 2 ]PF 6 , the Fe II atom is coordinated by two carbonyl groups, a triphenylphosphine ligand and a pentamethylcyclopentadienyl ligand in a typical piano-stool structure.

(η5-Cyclo­penta­dien­yl)[η4-(exo-5-pheny
(η5-Cyclo­penta­dien­yl)[η4-(exo-5-phenyl­ethyn­yl)-1,3-cyclo­penta­dien­yl]cobalt(II)
✍ Li, Li-Yan ;Gan, Quan ;Meng, Xiang-Gao ;Yu, Guang-Ao ;Liu, Sheng-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

In the crystal structure of the title compound, [Co(C 5 H 5 )-(C 13 H 10 )], the Co atom is connected to two five-membered rings. Both rings are disordered and were refined using a split model.

[μ-1κC1:2(C2,C3-η)-All­yl]tetra­carbonyl
[μ-1κC1:2(C2,C3-η)-All­yl]tetra­carbonyl-1κ2C,2κ2C-(1η5-cyclo­penta­dien­yl)(2η5-penta­methyl­cyclo­penta­dien­yl)rutheniumiron hexa­fluoro­phosphate
✍ Friedrich, Holger B. ;Changamu, Evans O. ;Rademeyer, Melanie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

In the molecule of the title compound, [FeRu(C 3 H 5 )(C 5 H 5 )-(C 10 H 15 )(CO) 4 ]PF 6 , two metal centers are bridged by an allyl chain, resulting in a chiral heterobimetallic molecular ion, with hexafluorophosphate as counter-ion. Both enantiomers are present in the crystal structure, forming a