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Dicarbon­yl(η5-penta­methyl­cyclo­penta­dien­yl)(triphenyl­phosphine)iron(II) hexa­fluoro­phosphate

✍ Scribed by Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
166 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Fe(C 10 H 15 )(C 18 H 15 P)(CO) 2 ]PF 6 , the Fe II atom is coordinated by two carbonyl groups, a triphenylphosphine ligand and a pentamethylcyclopentadienyl ligand in a typical piano-stool structure.

📜 SIMILAR VOLUMES

Carbon­yl(η5-cyclo­penta­dien­yl)(isocya
Carbon­yl(η5-cyclo­penta­dien­yl)(isocyano­triphenyl­borato-κC)(triphenyl­phosphine-κP)iron(II)
✍ Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

In the title compound, [Fe(C 5 H 5 )(C 19 H 15 BN)(C 18 H 15 P)(CO)], the Fe II atom is coordinated by a carbonyl group, a triphenylphosphine ligand, an isocyanotriphenylborate ligand and a cyclopentadienyl ligand in a piano-stool structure. Two crystallographically independent molecules exist in th

Dicarbon­yl(η5-cyclo­penta­dien­yl)(1-ph
Dicarbon­yl(η5-cyclo­penta­dien­yl)(1-phenyl-3,4-dimethyl­phospho­le)iron(II) tetra­fluoro­borate
✍ Reiss, Guido J. ;Ganter, Christian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 189 KB

The cation of the title compound, C 19 H 18 FeO 2 P + ÁBF 4 À or [Fe(C 5 H 5 )(C 12 H 13 P)(CO) 2 ]BF 4 , features a typical half-sandwich-type structure with four ligands roughly giving a tetrahedral coordination of the Fe ion.