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Dicarbon­yl(η5-cyclo­penta­dien­yl)(1-phenyl-3,4-dimethyl­phospho­le)iron(II) tetra­fluoro­borate

✍ Scribed by Reiss, Guido J. ;Ganter, Christian

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
189 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The cation of the title compound, C 19 H 18 FeO 2 P + ÁBF 4

À or [Fe(C 5 H 5 )(C 12 H 13 P)(CO) 2 ]BF 4 , features a typical half-sandwich-type structure with four ligands roughly giving a tetrahedral coordination of the Fe ion.

📜 SIMILAR VOLUMES

(η5-Cyclo­penta­dien­yl)[η4-(exo-5-pheny
(η5-Cyclo­penta­dien­yl)[η4-(exo-5-phenyl­ethyn­yl)-1,3-cyclo­penta­dien­yl]cobalt(II)
✍ Li, Li-Yan ;Gan, Quan ;Meng, Xiang-Gao ;Yu, Guang-Ao ;Liu, Sheng-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

In the crystal structure of the title compound, [Co(C 5 H 5 )-(C 13 H 10 )], the Co atom is connected to two five-membered rings. Both rings are disordered and were refined using a split model.