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[(1,2:5,6-η)-Cyclo­octa-1,5-diene]bis­[2,3,5,6-tetra­fluoro-4-(trifluoro­meth­yl)benzenethiol­ato]platinum(II)

✍ Scribed by Rivera, Guillermina ;Torrens, Hugo ;Bernès, Sylvain

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
175 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

{1,3-Bis(3,4,5-trimethoxy­benz­yl)-3,4,5
{1,3-Bis(3,4,5-trimethoxy­benz­yl)-3,4,5,6-tetra­hydro­pyrimidin-2-yl­idene}chloro(η4-cyclo­octa-1,5-diene)rhodium(I)
✍ Arslan, Hakan ;VanDerveer, Don ;Özdemir, İsmail ;Demir, Serpil ;Çetinkaya, Bekir 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 158 KB

In the title complex, [RhCl(C~8~H~12~)(C~24~H~32~N~2~O~6~)], the Rh atom is coordinated by a Cl atom, one C atom of the tetrahydropyrimidine ring and the two double bonds of cyclooctadiene. Each of the tetrahydropyrimidine and cyclooctadiene rings is puckered.

5,6-Dihydr­oxy-1,2,3,13-tetra­meth­oxy-6
5,6-Dihydr­oxy-1,2,3,13-tetra­meth­oxy-6,7-dimethyl-5,6,7,8-tetra­hydro­benzo[3,4]cyclo­octa­[1,2-f][1,3]­benzodioxol-5-yl benzoate sesquihydrate
✍ Xiong, Ying ;Gao, Wen-Yuan ;Deng, Ke-Zhong ;Chen, Hai-Xia ;Wang, Shu-Jun 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 204 KB

In the title compound, C 30 H 32 O 9 Á1.5H 2 O, the cyclooctadiene eight-membered ring adopts a twisted boat-chair conformation. O-HÁ Á ÁO hydrogen bonding helps to stabilize the crystal structure.