The crystal structure of the title compound, C 23 H 28 Br 4 O 6 , confirms that it consists of two hexasubstituted aromatic units linked by a central methylene group. The molecule lies on a crystallographic twofold axis that passes through the methylene bridging atom. Examination of the extended str
{1,3-Bis(3,4,5-trimethoxybenzyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene}chloro(η4-cycloocta-1,5-diene)rhodium(I)
✍ Scribed by Arslan, Hakan ;VanDerveer, Don ;Özdemir, İsmail ;Demir, Serpil ;Çetinkaya, Bekir
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 158 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [RhCl(C~8~H~12~)(C~24~H~32~N~2~O~6~)], the Rh atom is coordinated by a Cl atom, one C atom of the tetrahydropyrimidine ring and the two double bonds of cyclooctadiene. Each of the tetrahydropyrimidine and cyclooctadiene rings is puckered.
📜 SIMILAR VOLUMES
In the title molecule, C~11~H~11~FN~2~OS, conformational disorder is observed in the tetrahydropyrimidine ring and both components adopt half-chair conformations. In the crystal structure, the molecules are linked by C—H...O and N—H...S hydrogen bonds, forming a sheet-like structure parallel to the