(Hydridotripyrazolylborato)iodo{(1,2,5,6-η)-1-[(Z)-1-iodo-2-phenylethenyl]cycloocta-1,5-diene}ruthenium(II)–diiodine (2/1)
✍ Scribed by Slugovc, Christian ;Kirchner, Karl ;Mereiter, Kurt
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 391 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title complex, [RhCl(C~8~H~12~)(C~24~H~32~N~2~O~6~)], the Rh atom is coordinated by a Cl atom, one C atom of the tetrahydropyrimidine ring and the two double bonds of cyclooctadiene. Each of the tetrahydropyrimidine and cyclooctadiene rings is puckered.
In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent