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Carbon­yl(η5-cyclo­penta­dien­yl)(isocyano­triphenyl­borato-κC)(triphenyl­phosphine-κP)iron(II)

✍ Scribed by Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
122 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Fe(C 5 H 5 )(C 19 H 15 BN)(C 18 H 15 P)(CO)], the Fe II atom is coordinated by a carbonyl group, a triphenylphosphine ligand, an isocyanotriphenylborate ligand and a cyclopentadienyl ligand in a piano-stool structure. Two crystallographically independent molecules exist in the asymmetric unit; the Fe-CN, C N and CN-B bond distances are 1.866 (3), 1.157 (3) and 1.584 (4) A ˚, respectively, for one molecule, and 1.879 (3), 1.157 (3) and 1.587 (4) A ˚, respectively, for the other. metal-organic papers m1168 Nakazawa et al. [Fe(C 5 H 5 )(C 19 H 15 BN)(C 18 H 15 P)(CO)]

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